Silent Assassin is a a ranking at the end of a level. The very first mission you can get this is Mission 2: The King of Chinatown (since you can't get it in the prologue). The first time you can get this is in Mission 2: The King of Chinatown. To the right of the area where the target is, there is a area with chefs and they are selling food. Find the chef with the red apron (a female). Behind her is an odd looking dish with poisonous fish. After she turns her back, grab it. Now go North to where there is 2 chefs and a police guard. On the right, sneak in and find the disguise near the garbage. Walk to the middle area where the target has likely left. Poison his coffee and walk away. After he goes back and drinks the coffee, you are free to exit the level. You will also get the "Inconspicuous" achievement as well as "Whoops" if you had not already obtained it.
In the mission the king of chinatown search the market and look for fugu fish its on one of the market stalls to the right of where the king sits then go look for the drug which is in the dealers place and to the right of where to enter the market (easier option) down the slope and down some stair poison the drugs wait by the exit simple as that
One way of getting this is in Fight Night, got it last night actually without even realizing it. In the first part you have to take out the fighter to obtain The Patriot outfit, then go through the door on the right to fight Sanchez. At the end of the fight you'll get both "Faith Can Move Mountains" and "Silent Assassin" achievements.
This might of already been said.....Anyway the easiest way is to simply get the poison out of the fugu fish then when you have that go and poison the kings drugs that is down the stairs if you dont know where it is just follow kings drug dealer then reset and do it again.
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