Apparently, your CASIE augmentation doesn't work on everyone...
When 'the hacker' calls you after you take care of Burke and his men, if you are doing a Factory Zero playthrough, make a save. If not, then don't bother. Use your praxis to upgrade your Social Enhancer, otherwise known as CASIE. Continue to the mission marker where you come face to face with the hacker and when you are talking, when you have the option to activate pheromones, select Appease. This won't work on him and you'll get the achievement. If you want to keep things spoiler free, don't watch the video, but it speaks a thousand words.
For all of you wanting the right solution for this achievement read this:
You will need your Casie augmentation available to achieve this!
At the very end of the missing link dlc after killing the final boss you will talk to Quinn again on the harbor. during the conversation you will have the chance to use the Casie persuasion option, do so and Quinn will stop you before it has a chance to activate. Achievement will then pop up as you continue the conversation.