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After much frustration I just finally got Master Sniper. I tried aiming for the lip of the helmet/forehead and wasn't having any luck on Act 3: Chapter 1. I restarted my Xbox, and sat through the TV report cutscene at the very beginning and sure enough the lip of the helmet method worked first time I let that cutscene finish. My settings were easy difficulty with cheats enabled. Hope this helps somebody.
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